Issue 13, 1987

σ-η2 Transformation of an electron-rich thioarsenic heterocyclic ligand: X-ray crystal structure of [Mo(η2-AsSCH2CH2S)(CO)2(η-C5H5)]

Abstract

Photolysis of the complex [Mo(σ-[graphic omitted])(CO)3(η-C5H5)] causes elimination of carbon monoxide and formation of [Mo(η2-[graphic omitted])(CO)2(η-C5H5)] in which the ring behaves as a di-hapto, formally three-electron donor.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 983-984

σ-η2 Transformation of an electron-rich thioarsenic heterocyclic ligand: X-ray crystal structure of [Mo(η2-AsSCH2CH2S)(CO)2(η-C5H5)]

E. W. Abel, S. R. Allen, P. A. Bates, M. B. Hursthouse and B. Khandelwal, J. Chem. Soc., Chem. Commun., 1987, 983 DOI: 10.1039/C39870000983

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