Issue 12, 1987

Activation of benzene carbon–hydrogen bonds by palladium(II) acetate–dialkyl sulphide systems

Abstract

Benzene is directly activated by palladium(II) acetate-dialkyl sulphide systems at 70 °C to afford acetato-bridged diphenyltripalladium(II) complexes [(R2S)PhPd(µ-MeCO2)2Pd(µ-MeCO2)2PdPh(SR2)], which are regarded as intermediate species in the catalytic arylation of alkenes and carbonylation of arenes by palladium(II) acetate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 941-942

Activation of benzene carbon–hydrogen bonds by palladium(II) acetate–dialkyl sulphide systems

Y. Fuchita, K. Hiraki, Y. Kamogawa and M. Suenaga, J. Chem. Soc., Chem. Commun., 1987, 941 DOI: 10.1039/C39870000941

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