A novel p-tropoquinone methide-type compound has been synthesized; it has a high electron affinity and the molecule rotates about the exocyclic methylene double bond with a very low energy barrier in preference to the intercyclic single bond.
K. Takahashi, N. Namekata, K. Takase and T. Suzuki, J. Chem. Soc., Chem. Commun., 1987, 935 DOI: 10.1039/C39870000935
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