Issue 12, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and structural characterisation of [TlPt3(CO)3(PCy3)3][Rh(η-C8 H12)Cl2](Cy = cyclohexyl), a tetrahedral Pt3Tl cluster compound

Osayi J. Ezomo,   D. Michael P. Mingos  and  Ian D. Williams  

Abstract

The first example of a thallium–platinum metal cluster cation has been synthesised from TlI salts and [Pt3(CO)3(PCy3)3](Cy = cyclohexyl); in [TlPt3(CO)3(PCy3)3]+ the Tl atom caps the Pt3 triangle with Pt–Tl (average)= 3.038(1)Å.

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Article information

DOI
https://doi.org/10.1039/C39870000924
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 924-925

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Synthesis and structural characterisation of [TlPt3(CO)3(PCy3)3][Rh(η-C8 H12)Cl2](Cy = cyclohexyl), a tetrahedral Pt3Tl cluster compound

O. J. Ezomo, D. M. P. Mingos and I. D. Williams, J. Chem. Soc., Chem. Commun., 1987, 924 DOI: 10.1039/C39870000924

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