The carbon–carbon double bond or the nitro group of nitrobenzylidene malonic diethyl ester has been reduced selectively with Hantzsch ester using a metal ion catalyst or by sensitized photoirradiation, providing evidence of a one step hydride transfer and/or multistep hydrogen transfer mechanism respectively.
H. Xu, G. Deng and Q. Yu, J. Chem. Soc., Chem. Commun., 1987, 916 DOI: 10.1039/C39870000916
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