Issue 12, 1987

Formation of a trimethyldihydroperimidinium cation from proton sponge [1,8-bis(dimethylamino)naphthalene] during base-promoted reactions of rhodium and ruthenium complexes

Abstract

Proton sponge, in the presence of mer-RhCl3(dmso)3 or [RuCl(dppb)]2(µ-Cl)3(dmso = dimethyl sulphoxide, dppb = Ph2P[CH2]4PPh2), generates (via a net hydride loss from one methyl group) the 1,1,3-trimethyl-2,3-dihydroperimidinium cation, which is isolated as the counter-ion in complexes containing the anions trans-[RhCl4(dmso)2] and {[RuCl(dppb)]2(µ-Cl)3}.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 894-895

Formation of a trimethyldihydroperimidinium cation from proton sponge [1,8-bis(dimethylamino)naphthalene] during base-promoted reactions of rhodium and ruthenium complexes

S. N. Gamage, R. H. Morris, S. J. Rettig, D. C. Thackray, I. S. Thorburn and B. R. James, J. Chem. Soc., Chem. Commun., 1987, 894 DOI: 10.1039/C39870000894

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