Issue 10, 1987

ortho-Functionalisation of aryl ketones with alkenes; synthesis of 3-methylindene-2-carboxylates and 3-substituted-2-acetylthiophenes from η2-(o-acetylaryl)tetracarbonylmanganese compounds with alkenes in the presence of palladium(II)

Abstract

η2-(o-Acetylaryl)tetracarbonylmanganese compounds in the presence of PdII undergo new synthetically valuable coupling reactions with methyl acrylate, methyl vinyl ketone, acrylaldehyde, allyl alcohol, and acrylonitrile.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 761-762

ortho-Functionalisation of aryl ketones with alkenes; synthesis of 3-methylindene-2-carboxylates and 3-substituted-2-acetylthiophenes from η2-(o-acetylaryl)tetracarbonylmanganese compounds with alkenes in the presence of palladium(II)

L. H. P. Gommans, L. Main and B. K. Nicholson, J. Chem. Soc., Chem. Commun., 1987, 761 DOI: 10.1039/C39870000761

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