Hydride addition to acyclic α-alkoxy and α,β-dialkoxy ketone oximes using aluminium hydride reagents proceeds in an anti-selective manner under α-chelation control, providing chiral anti amines.
H. Lida, N. Yamazaki and C. Kibayashi, J. Chem. Soc., Chem. Commun., 1987, 746 DOI: 10.1039/C39870000746
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