Alkyl trimethylsilylacetates readily undergo thermal elimination to give ketene and trimethylsilyl alkyl ethers; Arrhenius data have been obtained for this new unimolecular first-order reaction which involves a semi-concerted four-centre process.
R. Taylor, J. Chem. Soc., Chem. Commun., 1987, 741 DOI: 10.1039/C39870000741
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