Carbon-13 n.m.r. studies utilizing [1-13C]-D-glucose demonstrate that the apparent C-2 epimerization catalysed by [Ni(H2O)2(tmen)2]Cl2(tmen =N,N,N′-trimethylethylenediamine) in fact proceeds via a molecular rearrangement in which the C-1 carbon label is found at the C-2 position of the product mannose.
R. E. London, J. Chem. Soc., Chem. Commun., 1987, 661 DOI: 10.1039/C39870000661
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...