Coupling of two phospha-alkyne units via a carbonyl group, in the addition across the RhRh double bond of [Rh2(CO)2(η5-C5Me5)2], crystal and molecular structure of the complex [Rh2(CO)(η5-C5Me5)2{PCRC(O)CRP}](R = adamantyl)

Peter B. Hitchcock; Mohd Jamil Maah; John F. Nixon

doi:10.1039/C39870000658

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Coupling of two phospha-alkyne units via a carbonyl group, in the addition across the RhRh double bond of [Rh₂(CO)₂(η⁵-C₅Me₅)₂], crystal and molecular structure of the complex [Rh₂(CO)(η⁵-C₅Me₅)₂{PCRC(O)CRP}](R = adamantyl)

Peter B. Hitchcock, Mohd Jamil Maah and John F. Nixon

Abstract

The novel ligating unit P [double bond, length half m-dash] CRC(O)CRP (R = adamantyl) has been obtained from two phospha-alkynes RC [triple bond, length half m-dash] P on treatment with [Rh₂(CO)₂(η⁵-C₅Me₅)₂].

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DOI: https://doi.org/10.1039/C39870000658
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1987, 658-659

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Coupling of two phospha-alkyne units via a carbonyl group, in the addition across the RhRh double bond of [Rh₂(CO)₂(η⁵-C₅Me₅)₂], crystal and molecular structure of the complex [Rh₂(CO)(η⁵-C₅Me₅)₂{PCRC(O)CRP}](R = adamantyl)

P. B. Hitchcock, M. J. Maah and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1987, 658 DOI: 10.1039/C39870000658

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Journal of the Chemical Society, Chemical Communications

Coupling of two phospha-alkyne units via a carbonyl group, in the addition across the RhRh double bond of [Rh₂(CO)₂(η⁵-C₅Me₅)₂], crystal and molecular structure of the complex [Rh₂(CO)(η⁵-C₅Me₅)₂{PCRC(O)CRP}](R = adamantyl)

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Coupling of two phospha-alkyne units via a carbonyl group, in the addition across the RhRh double bond of [Rh₂(CO)₂(η⁵-C₅Me₅)₂], crystal and molecular structure of the complex [Rh₂(CO)(η⁵-C₅Me₅)₂{PCRC(O)CRP}](R = adamantyl)

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