Issue 9, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation and crystal structure of [ClPtNMe2NHCH2CHPPh2CH2CH2PPh2]Cl containing a novel tridentate ylide ligand formed by intramolecular phosphinovinylation

Andrew M. Herring,   David P. Markham,   Bernard L. Shaw  and  Mark Thornton-Pett  

Abstract

Treatment of cis-[PtCl2(PPh2CH[double bond, length half m-dash]CH2)2] with Me2NNH2 gives the title compound, formed by successive conjugate additions to the vinyl groups, including attack by one P-atom on a vinyl group of an adjacent co-ordinated PPh2CH[double bond, length half m-dash]CH2 ligand: some reactions of the title compound are described.

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Article information

DOI
https://doi.org/10.1039/C39870000643
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 643-644

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Formation and crystal structure of [ClPtNMe2NHCH2CHPPh2CH2CH2PPh2]Cl containing a novel tridentate ylide ligand formed by intramolecular phosphinovinylation

A. M. Herring, D. P. Markham, B. L. Shaw and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1987, 643 DOI: 10.1039/C39870000643

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