Issue 8, 1987

Correlations between the transfer thermodynamics of simple electrolytes and structural parameters with particular reference to steric hindrance

Abstract

Structural studies on Li+, Na+, Ca2+, and Ag+ in aqueous solution by neutron diffraction and computer simulation explain certain trends in the free energies of transfer of these ions from water to mixed aqueous solvents; in particular, the thermodynamic evidence of decreasing steric hindrance to solvation by bulky ligands in the order Li+ > Na+ > Ag+ is consistent with the structures of the ion-complexes in aqueous solution.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 611-613

Correlations between the transfer thermodynamics of simple electrolytes and structural parameters with particular reference to steric hindrance

D. Feakins, B. E. Hickey, M. Knox, P. J. McCarthy and W. E. Waghorne, J. Chem. Soc., Chem. Commun., 1987, 611 DOI: 10.1039/C39870000611

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