Issue 8, 1987

The generation and microwave spectrum of propadienethione, H2C[double bond, length half m-dash]C[double bond, length half m-dash]C[double bond, length half m-dash]S

Abstract

The third member of the cumulenethione series, H2CnS, propadienethione, has been produced by pyrolysis of cyclopenteno-1,2,3-thiadiazole and detected by microwave spectroscopy which provided rotational parameters for the 32S and 34S isotopomers, the dipole moment [2.064(8) Debye], and an indication that propadienethione is a planar molecule of C2v symmetry.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 573-574

The generation and microwave spectrum of propadienethione, H2C[double bond, length half m-dash]C[double bond, length half m-dash]C[double bond, length half m-dash]S

R. D. Brown, P. D. Godfrey, P. S. Elmes and D. McNaughton, J. Chem. Soc., Chem. Commun., 1987, 573 DOI: 10.1039/C39870000573

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