Pathways in nucleophilic fission of hydroxythietanes are determined by the oxidation state of sulphur; for eliminative fission, activation parameters, substituent effects, and comparison with unstrained analogues all suggest a greater degree of ring cleavage in the transition structure for thietanes than for cyclobutanes.
D. J. Young and C. J. M. Stirling, J. Chem. Soc., Chem. Commun., 1987, 552 DOI: 10.1039/C39870000552
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