SCHEDULED MAINTENANCE:
The successive treatment of borane in tetrahydrofuran with sterically-hindered internal alkenes, 1,4-dichlorobut-2-yne, and alkyl-lithium has provided good yields of 2-alkylbuta-1,3-dienes whose alkyl groups are derived from the alkene.
A. Arase and M. Hoshi, J. Chem. Soc., Chem. Commun., 1987, 531 DOI: 10.1039/C39870000531
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