Vanadium K-edge XANES and EXAFS studies revealed that the surface vanadium oxide species of V2O5/SiO2 prepared by impregnating silica with a basic solution (NaOH) of ammonium metavandate is dominantly an isolated tetrahedral VO4 species, which brings about an enhanced photocatalytic activity.
T. Tanaka, Y. Nishimura, S. Kawasaki, T. Funabiki and S. Yoshida, J. Chem. Soc., Chem. Commun., 1987, 506 DOI: 10.1039/C39870000506
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