Issue 6, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

A double cluster of ruthenium and boron; [1-η2-{(η6-C6Me6)2Ru2H4}-isocloso-1-RuB10H8-2,3-(OEt)2]

Mark Bown,   Xavier L. R. Fontaine,   Norman N. Greenwood,   Peter MacKinnon,   John D. Kennedy  and  Mark Thornton-Pett  

Abstract

The novel double cluster compound [{(η6-C6Me6)2Ru2H4}RuB10H8(OEt)2], obtained in 31% yield as an unexpected product from the reaction between the mononuclear ruthenium complex arachno-[(η6-C6Me6)ClRuB3H8] and closo-[B10H10]2– in ethanol, exhibits a unique (non-carbonyl containing) triangular {Ru3} cluster and a closo-type eleven-vertex {RuB10} cluster conjoined at a common Ru atom.

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Article information

DOI
https://doi.org/10.1039/C39870000442
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 442-443

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A double cluster of ruthenium and boron; [1-η2-{(η6-C6Me6)2Ru2H4}-isocloso-1-RuB10H8-2,3-(OEt)2]

M. Bown, X. L. R. Fontaine, N. N. Greenwood, P. MacKinnon, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1987, 442 DOI: 10.1039/C39870000442

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