Pyrolysis of endo- and exo-bicyclo[2.2.1]heptane-2-thiols yields tricyclo[2.2.1.02,6]heptane and bicyclo[2.2.1]hept-2-ene via competing carbene and radical mechanisms.
D. E. Johnson and A. F. Dimian, J. Chem. Soc., Chem. Commun., 1987, 416 DOI: 10.1039/C39870000416
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