Issue 5, 1987

Formyl onium salts: synthesis and decomposition pathways

Abstract

Isolable formyl-pyridinium and -imidazolium salts are generated by treating Lewis acid–base pairs of type Me3SiA–N-heterocycle(A = leaving group) with acetic formic anhydride; their thermal and base-catalysed decarbonylation is discussed in the light of theoretical data.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 317-318

Formyl onium salts: synthesis and decomposition pathways

R. Weiss and R. Roth, J. Chem. Soc., Chem. Commun., 1987, 317 DOI: 10.1039/C39870000317

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