Di-n-butyltin oxide efficiently catalyses the rearrangement of 3-hydroxy-2-oxocarboxylic acid esters into the corresponding 2-hydroxy-3-oxo-esters, in a reaction that simulates the reversible rearrangement catalysed by the enzyme reductiosomerase.
D. H. G. Crout and D. L. Rathbone, J. Chem. Soc., Chem. Commun., 1987, 290 DOI: 10.1039/C39870000290
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