Three possible stereoisomers of 14,15-dinoreudesmanolide, the structure of which consists of an α-methylene-γ-lactone ring fused to a trans-decalin ring, have been synthesized from a dialdehyde monoacetal viaα-trimethylsilylmethyl-α,β-unsaturated esters.
C. Kuroda, S. Shimizu and J. Y. Satoh, J. Chem. Soc., Chem. Commun., 1987, 286 DOI: 10.1039/C39870000286
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