Issue 4, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Two-fragment addition of borohydride to iron complexes: synthesis of dithioformate iron complexes with B–H–Fe bond interaction. X-Ray structural characterization of Fe[η3-HC(SMe)S → B(H)H2](CO)(PMe3)2

Dilip V. Khasnis,   Loïc Toupet  and  Pierre H. Dixneuf  

Abstract

Reaction of Fe(X)(µ2CS2R)(CO)(PR3)2(X = Cl, I) complexes with NaBH4 leads to both hydride and BH3 addition with the formation of dithiofromate–iron(O) Fe[µ3-HC(SR)S → BH3](CO)(PR3)2 complexes (4) containing an agostic B–H–Fe interaction; the addition of pyridine to (4) liberates a 16 electron-iron(O) moiety by trapping of the BH3 unit.

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Article information

DOI
https://doi.org/10.1039/C39870000230
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 230-231

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Two-fragment addition of borohydride to iron complexes: synthesis of dithioformate iron complexes with B–H–Fe bond interaction. X-Ray structural characterization of Fe[η3-HC(SMe)S → B(H)H2](CO)(PMe3)2

D. V. Khasnis, L. Toupet and P. H. Dixneuf, J. Chem. Soc., Chem. Commun., 1987, 230 DOI: 10.1039/C39870000230

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