Issue 3, 1987

Reinvestigation of the reaction of nitrenes with naphthalene. Formation of 1H-1-benzazepine and 3H-3-benzazepine

Abstract

Thermally generated methoxycarbonylnitrene in naphthalene gave 1H-1-benzazepine and 3H-3-benzazepine derivatives, the yields of which increased with increased nitrogen pressure; formation of methyl 1-naphthyl-carbamate and the reaction path are also discussed.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 197-199

Reinvestigation of the reaction of nitrenes with naphthalene. Formation of 1H-1-benzazepine and 3H-3-benzazepine

K. Satake, H. Mizushima, M. Kimura and S. Morosawa, J. Chem. Soc., Chem. Commun., 1987, 197 DOI: 10.1039/C39870000197

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