The conjugate addition of phenylselenomethyl-lithium to the α,β-unsaturated lactone (4) was a key step in a short synthesis of (±)-benzoylselenopederic acid (2); union of (2) and (±)-benzoylpedamide (3) by a modification of known procedures gave (±)-pederin (1).
T. Willson, P. Kocieński, A. Faller and S. Campbell, J. Chem. Soc., Chem. Commun., 1987, 106 DOI: 10.1039/C39870000106
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