(py)Fe(CO)4(py = pyridine) is formed on carbonylation of [Fe(py)6][Fe4(CO)13], and the 56 electron tetranuclear cluster [(py)2FeFe(CO)4]2, the crystal structure of which has been determined, is produced on dissolving (py)Fe(CO)4 in organic solvents; it behaves as a bifunctional molecule in reducing CO2 to CO, FeCO3 being formed during this reaction.
G. Fachinetti, G. Fochi, T. Funaioli and P. F. Zanazzi, J. Chem. Soc., Chem. Commun., 1987, 89 DOI: 10.1039/C39870000089
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