Stereochemical studies of cycloadducts produced from primary and secondary α-amino acids, aldehydes, and N-methylmaleimide indicate they usually arise from stereospecific or highly stereoselective formation of the anti-isomer of an intermediate azomethine ylide.
R. Grigg, S. Surendrakumar, S. Thianpatanagul and D. Vipond, J. Chem. Soc., Chem. Commun., 1987, 47 DOI: 10.1039/C39870000047
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