SCHEDULED MAINTENANCE
Reactions of 5-ethenyl-3,4-dihydro-4-isopropylidene-2,2-dimethyl-2H-pyrrole (2) with a variety of alcohols led to formation of the 1,4-addition products (4) rather than the 2-alkoxypyrrolidine derivatives [e.g.(7)]. On distillation the adducts (4) suffered thermal rearrangement to the 5-(2-alkoxyethyl)-3,4-dihydro-2H-pyrroles (5).
C. A. Zezza and M. B. Smith, J. Chem. Soc., Perkin Trans. 2, 1986, 945 DOI: 10.1039/P29860000945
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