Issue 0, 1986

Chemical transformation of protoberberines. Part 9. A biomimetic synthesis of oxychelerythrine, dihydrochelerythrine, and chelerythrine from berberine

Abstract

Fully aromatised benzo[c]phenanthridine alkaloids, oxychelerythrine (4), dihydrochelerythrine (9), and chelerythrine (10) have been efficiently synthesized from berberine (1), a protoberberine alkaloid, via oxidative C(6)–N bond cleavage, followed by recyclisation between the C-6 and C-13 positions of (1) by a biogenetic process.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1986, 2253-2256

Chemical transformation of protoberberines. Part 9. A biomimetic synthesis of oxychelerythrine, dihydrochelerythrine, and chelerythrine from berberine

M. Hanaoka, T. Motonishi and C. Mukai, J. Chem. Soc., Perkin Trans. 1, 1986, 2253 DOI: 10.1039/P19860002253

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