Beckmann rearrangement of Δ4-6-hydroxyimino steroids gave solely the products of vinyl migration. Compounds having a 3-hydroxy or 3-acetoxy group suffer elimination of the substituent during the reaction.
M. Anastasia, P. Allevi, P. Ciuffreda, A. Fiecchi and A. Scala, J. Chem. Soc., Perkin Trans. 1, 1986, 2123 DOI: 10.1039/P19860002123
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