SCHEDULED MAINTENANCE
The oxidation of a series of steroids by the Gif system gives, almost without exception, the 20-ketone as major isolated product. The side-chain cleavage is made more selective by modification of rings A or B. The oxidation of oleana-1,12-diene-3,11-dione has also been studied and the two principal products have been identified.
D. H. R. Barton, J. Boivin and C. H. Hill, J. Chem. Soc., Perkin Trans. 1, 1986, 1797 DOI: 10.1039/P19860001797
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