SCHEDULED MAINTENANCE
An efficient three-step synthesis of the coumestan, tuberostan (1), from the benzyloxyisoflavone (2) is described. The synthesis involves a single-step ‘hydrogenative cyclisation’ of the isoflavone (2) to the pterocarpan, (±)-isomedicarpin (5)
A. V. K. Prasad, R. S. Kapil and S. P. Popli, J. Chem. Soc., Perkin Trans. 1, 1986, 1561 DOI: 10.1039/P19860001561
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