Issue 0, 1986

Palladium-catalysed allylic alkylation of allylic nitro compounds with stabilized carbanions

Abstract

In the presence of a catalytic amount of Pd(PPh3)4, allylic nitro compounds (1) undergo allylic alkylation with stabilized carbanions to give a mixture of two regio-isomers (2) and (3). The product ratio (2) : (3) is controlled both by the nature of the substituents of π-allyl unit and the steric factors of the nucleophiles and ligands.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1986, 1439-1443

Palladium-catalysed allylic alkylation of allylic nitro compounds with stabilized carbanions

N. Ono, I. Hamamoto and A. Kaji, J. Chem. Soc., Perkin Trans. 1, 1986, 1439 DOI: 10.1039/P19860001439

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