The photoreduction of the eosin analogue (1; R = H) by tribenzylamine under anaerobic conditions is found to produce a high yield of the cross-coupled product (3; R = H) which readily reoxidises to the starting dye. The formation of (3; R = H), which is considered to take place in the initial solvent cage, has implications for earlier kinetic studies on the photoreduction of related dyes.
K. Phillips and G. Read, J. Chem. Soc., Perkin Trans. 1, 1986, 671 DOI: 10.1039/P19860000671
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