Both (R)- and (S)-1,2-isopropylideneglyceraldehydes (1) and (18) are shown to be useful, inexpensive chiral starting materials for syntheses of α-methylene-γ-butyrolactones (15) and (28) which are potential intermediates for biologically important sesquiterpene lactones.
T. Suzuki, E. Sato, S. Kamada, H. Tada, K. Unno and T. Kametani, J. Chem. Soc., Perkin Trans. 1, 1986, 387 DOI: 10.1039/P19860000387
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