The kinetics of the bimolecular reaction of O(3P) atoms with CF2(X1A1) radicals have been investigated. Ground state CF2 was generated by infrared multiple photon dissociation of CF2HCl in the presence of an excess of O atoms, and its decay was measured by time-resolved laser-induced fluorescence. The rate constant at 295 K for the process O(3P)+ CF2(X1A1)→ products was measured as (1.75 ± 0.35)× 10–11 cm3 molecule–1 s–1.
G. Hancock, P. D. Harrison and A. J. MacRobert, J. Chem. Soc., Faraday Trans. 2, 1986, 82, 647 DOI: 10.1039/F29868200647
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