Issue 9, 1986
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Photocatalytic dehydrogenation of liquid propan-2-ol by TiO2. Part 2.—Mechanism

Ian M. Fraser  and  James R. MacCallum  

Abstract

The photodehydrogenation of propan-2-ol mediated by TiO2 has been studied. Using basic additives it has been established that the sites responsible for the bulk of the reaction are acidic in nature. A fibre-optic monitoring system has been used to study changes in absorption of radiation by the TiO2 in the presence of N2, O2 and H2O2. It is concluded that the active sites are Ti4+ ions. A mechanism involving O–2 and H2O2 is proposed.

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Article information

DOI
https://doi.org/10.1039/F19868202747
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1986,82, 2747-2754

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Photocatalytic dehydrogenation of liquid propan-2-ol by TiO2. Part 2.—Mechanism

I. M. Fraser and J. R. MacCallum, J. Chem. Soc., Faraday Trans. 1, 1986, 82, 2747 DOI: 10.1039/F19868202747

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