ENDOR Spectroscopy of bis(pentane-2,4-dionato)copper(II) and bis(hexafluoropentane-2,4-dionato)copper(II)
Abstract
A single-crystal ENDOR study of [Cu(pd)2] in [Pd(pd)2](pd = pentane-2,4-dionato) has been carried out. Tensors for all protons in the molecule have been determined together with one, the largest in magnitude, associated with the γ-proton of a neighbouring [Pd(pd)2] molecule. Frozen-solution ENDOR spectra of [Cu(pd)2] and of the hexafluoro derivative have also been determined and hyperfine coupling to protons and fluorine assigned.
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