Binuclear [Co2(RCO2)4L2] and trinuclear [Co3(RCO2)6L2] cobalt(II) carboxylate complexes have been prepared (R = unsaturated alkyl, L = sterically hindered amine). The roles of electronic and steric effects on the formation of oligonuclear cobalt(II) carboxylates are discussed. The temperature dependence of their antiferromagnetism shows variations as R and L are altered.
I. R. Little, B. P. Straughan and P. Thornton, J. Chem. Soc., Dalton Trans., 1986, 2211 DOI: 10.1039/DT9860002211
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