Issue 8, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reduction–oxidation properties of organotransition-metal complexes. Part 24. The oxidative dimerisation of [Ru(CO)2L(η4-cot)](L = CO or PPh3, cot = cyclo-octatetraene)

Neil G. Connelly,   Paul G. Graham  and  John B. Sheridan  

Abstract

Electrochemical studies show that [Ru(CO)2L(η4-cot)](1, L = CO or PPh3, cot = cyclo-octatetraene) undergoes a diffusion-controlled, but irreversible, one-electron oxidation at a platinum-bead electrode in CH2Cl2. The reaction of [Fe(η-C5H5)2][PF6] with (1, L = PPh3) in CH2Cl2 gives [Ru2(CO)4(PPh3)2(η2,η3: η′2,η′3-C16H16)][PF4]2via the C–C bond coupling of the radical cation [Ru(CO)2(PPh3)(C8H8)]+.

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Article information

DOI
https://doi.org/10.1039/DT9860001619
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 1619-1621

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Reduction–oxidation properties of organotransition-metal complexes. Part 24. The oxidative dimerisation of [Ru(CO)2L(η4-cot)](L = CO or PPh3, cot = cyclo-octatetraene)

N. G. Connelly, P. G. Graham and J. B. Sheridan, J. Chem. Soc., Dalton Trans., 1986, 1619 DOI: 10.1039/DT9860001619

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