Issue 5, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis of heterotrimetallic complexes containing M–Hg–Pt (M = Pt, Fe, Mn, or Co) arrays

Oriol Rossell,   Miquel Seco  and  Immaculada Torra  

Abstract

Heterotrimetallic complexes [Hg{PtR(PPh3)2}2](R = 2,3,4-C6H2Cl3, 2,4,6-C6H2Cl3, 2,3,5,6-C6HCl4, or C6Cl5) have been prepared by reaction of [Pt(CH2[double bond, length half m-dash]CH2)(PPh3)2] with [RHg–PtR(PPh3)2]. From the reactions of [Hg{Pt(C6Cl5)(PPh3)2}2] with [Hg{Fe(CO)2(η5-C5H5)}2], [Hg{Mn(CO)5}2], and [Hg{Co(CO)4}2], the complexes [(η5-C5H5)(CO)2Fe–Hg–Pt(C6Cl5)(PPh3)2], [(CO)5Mn–Hg–Pt(C6Cl5)(PPh3)2], and [(CO)4Co–Hg–Pt(C6Cl5)(PPh3)2] were isolated. The scope of these reactions is discussed. All the compounds were characterized by i.r. and 31P n.m.r. spectroscopy.

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Article information

DOI
https://doi.org/10.1039/DT9860001011
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 1011-1014

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Synthesis of heterotrimetallic complexes containing M–Hg–Pt (M = Pt, Fe, Mn, or Co) arrays

O. Rossell, M. Seco and I. Torra, J. Chem. Soc., Dalton Trans., 1986, 1011 DOI: 10.1039/DT9860001011

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