Issue 2, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

Tertiary phosphine aluminohydride complexes of ruthenium(II) and osmium(II)

Andrew R. Barron  and  Geoffrey Wilkinson  

Abstract

The interaction of dichloro tertiary phosphine complexes of ruthenium(II) and osmium(II) with LiAlH4 in ethers has afforded the complexes L3HM(µ-H)2AlH(µ-H)2AlH(µ-H)2MHL3 where M = Ru, L = PMe3, PEtPh2, or PPh3; M = Os, L = PMe3 or PPh3. Interaction of tetramethylethylenediamine with [(Me3P)3HRuAlH4]2 gives the complex [(Me3P)3HRu]2AlH5. Proton, 31P, and 27Al n.m.r. spectra are reported and the fluxional behaviour of the complexes discussed.

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Article information

DOI
https://doi.org/10.1039/DT9860000287
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 287-289

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Tertiary phosphine aluminohydride complexes of ruthenium(II) and osmium(II)

A. R. Barron and G. Wilkinson, J. Chem. Soc., Dalton Trans., 1986, 287 DOI: 10.1039/DT9860000287

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