Issue 24, 1986

Observations on the reductive deoxygenation of aryl and α,β-unsaturated carbonyl compounds with chlorotrimethylsilane and zinc

Abstract

Reductive McMurry-type dicarbonyl coupling of certain aryl and α,β-unsaturated carbonyl compounds to give alkenes can be accomplished using chlorotrimethylsilane and zinc by a novel mechanism which does not involve pinacolic coupling and diol deoxygenation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1803-1805

Observations on the reductive deoxygenation of aryl and α,β-unsaturated carbonyl compounds with chlorotrimethylsilane and zinc

A. K. Banerjee, M. C. S. de Carrasco, C. S. V. Frydrych-Houge and W. B. Motherwell, J. Chem. Soc., Chem. Commun., 1986, 1803 DOI: 10.1039/C39860001803

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