Observations on the reductive deoxygenation of aryl and α,β-unsaturated carbonyl compounds with chlorotrimethylsilane and zinc
Abstract
Reductive McMurry-type dicarbonyl coupling of certain aryl and α,β-unsaturated carbonyl compounds to give alkenes can be accomplished using chlorotrimethylsilane and zinc by a novel mechanism which does not involve pinacolic coupling and diol deoxygenation.