Issue 24, 1986

Use of hydrogen selenide for synthesis of binuclear palladium complexes containing bridging selenide, and their conversion into novel dimetallic selenoxides

Abstract

The complexes [Pd2Cl2{µ-PPh2CH(R)PPh2}2], where R = H or Me, react with H2Se or elemental Se to yield the bridging-selenide derivatives [Pd2Cl2(µ-Se){µ-PPh2CH(R)PPh2}2]; these, on treatment with ButOOH, yield the corresponding µ-SeO (dimetallic selenoxide) species.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1750-1751

Use of hydrogen selenide for synthesis of binuclear palladium complexes containing bridging selenide, and their conversion into novel dimetallic selenoxides

G. Besenyei, C. Lee and B. R. James, J. Chem. Soc., Chem. Commun., 1986, 1750 DOI: 10.1039/C39860001750

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