Issue 24, 1986

Photochemistry, spectroscopy, and X-ray structure of an intermolecular charge-transfer complex between an organic substrate and a polyoxometallate, α-H3PMo12O40·6(tetramethylurea)

Abstract

A photosensitive complex between an organic substrate, 1,1,3,3-tetramethylurea (TMU), and the heteropoly acid, α-H3PMo12O40 of stoicheiometry [(TMU)2H]3PMo12O40, (1), has been characterized in solution and in the solid state; irradiation into the low energy absorption bands of (1) in solution or in the solid state results in the immediate photoreduction of the polyoxometallate by the TMU.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1747-1748

Photochemistry, spectroscopy, and X-ray structure of an intermolecular charge-transfer complex between an organic substrate and a polyoxometallate, α-H3PMo12O40·6(tetramethylurea)

C. M. Prosser-McCartha, M. Kadkhodayan, M. M. Williamson, D. A. Bouchard and C. L. Hill, J. Chem. Soc., Chem. Commun., 1986, 1747 DOI: 10.1039/C39860001747

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