Issue 23, 1986

Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh23-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H4NS2= benzothiazole-2-thiolate)

Abstract

The complex [{Rh(µ2-C7H4NS2)(cod)}2] reacts with compounds of the group 11 metals to give heterotrinuclear complexes, one of which, the title compound, has been characterized by X-ray diffraction methods showing short Rh–Ag separations in a bent arrangement.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1737-1738

Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh23-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H4NS2= benzothiazole-2-thiolate)

M. A. Ciriano, L. A. Oro, J. J. Pérez-Torrente, A. Tiripicchio and M. Tiripicchio-Camellini, J. Chem. Soc., Chem. Commun., 1986, 1737 DOI: 10.1039/C39860001737

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