Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh2(µ3-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H4NS2= benzothiazole-2-thiolate)
Abstract
The complex [{Rh(µ2-C7H4NS2)(cod)}2] reacts with compounds of the group 11 metals to give heterotrinuclear complexes, one of which, the title compound, has been characterized by X-ray diffraction methods showing short Rh–Ag separations in a bent arrangement.