The highly regioselective reaction of postulated 1-methylseleno-allyl cations with pyrrole permits the one-pot synthesis of a series of novel prophyrins; alternatively, β-methylcrotonaldehyde gives (5a).
L. Hevesi, M. Renard and G. Proess, J. Chem. Soc., Chem. Commun., 1986, 1725 DOI: 10.1039/C39860001725
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