The i.r. spectra of the clusters [M4(µ-N)(CO)12(µ-L)](M = Ru, L = H, NCO, No; M = Os, L = H) and [Ru4(µ4-N)(CO)11(µ-H)3] have been measured, and the vibrational modes involving the semi-interstitial nitride ligand are assigned; the use of these compounds as models for atomic nitrogen chemisorbed on (110) surfaces of f.c.c. metals is discussed.
C. E. Anson, J. P. Attard, B. F. G. Johnson, J. Lewis, J. M. Mace and D. B. Powell, J. Chem. Soc., Chem. Commun., 1986, 1715 DOI: 10.1039/C39860001715
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