Issue 23, 1986

Iridium(III) hydrides derived from an iridium(I) substrate by oxidative addition and cyclometallation of germanium(II) bis(trimethylsilyl)amide; X-ray structures of [{CH2Me2SiN(R)(NR2)Ge}HIr(µ-Cl)2{Ge(NR2)N(R)SiMe2CH2}IrH{Ge(NR2)2}] and [lr{GeCl(NR2)N(R)SiMe2CH2}(CO)2H{Ge(NR2)2}](R = SiMe3)

Abstract

Treatment of [{Ir(η-C8H14)2(µ-Cl)}2] with Ge(NR2)2 in n-C6H14 at 20 °C (C8H14= cyclo-octene, R = SiMe3) in the absence or presence of CO leads to [{[graphic ommitted]H{Ge(NR2)2}](1) or [[graphic ommitted](CO)2H{Ge(NR2)2}](2), respectively; the Ir–Ge distances in (1) and (2) range from 2.325(3) to 2.470(3)Å.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1689-1690

Iridium(III) hydrides derived from an iridium(I) substrate by oxidative addition and cyclometallation of germanium(II) bis(trimethylsilyl)amide; X-ray structures of [{CH2Me2SiN(R)(NR2)Ge}HIr(µ-Cl)2{Ge(NR2)N(R)SiMe2CH2}IrH{Ge(NR2)2}] and [lr{GeCl(NR2)N(R)SiMe2CH2}(CO)2H{Ge(NR2)2}](R = SiMe3)

S. M. Hawkins, P. B. Hitchcock, M. F. Lappert and A. K. Rai, J. Chem. Soc., Chem. Commun., 1986, 1689 DOI: 10.1039/C39860001689

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