The reaction of [H3Os4(CO)12(NCMe)2]+ with [N(PPh3)2]NO2 yields [HOs4(CO)12{µ3-N(CO)Me}]– by a novel conversion of an acetonitrile ligand into an amido group on the cluster surface; the anion reacts with [MPPh3]+(M = Au or Cu) to produce the neutral derivatives [HOs4(CO)12{µ3-N(CO)Me}(MPPh3)] which have been characterised by X-ray diffraction.
J. Puga, R. A. Sánchez-Delgado, J. Ascanio and D. Braga, J. Chem. Soc., Chem. Commun., 1986, 1631 DOI: 10.1039/C39860001631
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